Carbamate hydrolysis：Elimination–addition mechanism for the hydrolysis ...
Elimination–addition mechanism for the hydrolysis ...
由AFHegarty著作·1973·被引用103次—Thehydrolyticconversionofarylcarbamatestoaminesisbasecatalysedandevidenceispresentedthattheprocessinvolvesan1cBeliminationwiththe ...。其他文章還包含有：「Basichydrolysisofcarbamatetoamineinaqueousethanol」、「HydrolysisMechanismofCarbamateMethomylbyaNovel...」、「Hydrolysisofacarbamatetriggeredbycoordination...」、「OrganicCarbamatesinDrugDesignandMedicinalChe...
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Basic hydrolysis of carbamate to amine in aqueous ethanol
https://cssp.chemspider.com
The aqueous potassium hydroxide/ethanol medium allows solubility of both base and organic carbamate, facilitating hydrolysis. By entirely ...
Hydrolysis Mechanism of Carbamate Methomyl by a Novel ...
https://www.mdpi.com
The hydrolysis process involves two steps. In the first step, the H1 of Ser157 transfers to His284, while the O1 on the Ser157 attacks the ...
Hydrolysis of a carbamate triggered by coordination ...
https://pubs.rsc.org
The reaction of the carbamate ligand H2L with chloride metal salts (M = Ni, Cu, Zn, Cd) leads to the coordination of the metal ions to the ligand, causing ...
Organic Carbamates in Drug Design and Medicinal Chemistry
https://pubs.acs.org
Fast hydrolysis of carbamate-bearing drugs may result in weak or shortened activity. On the contrary, carbamate-based prodrugs must undergo ...
Rates of hydrolysis of carbamate and carbonate esters in ...
https://onlinelibrary.wiley.co
The data seemed to indicate two mechanisms for the hydrolysis of the carbamates: that initiated by an hydroxyl ion attachment on the central carbon atom followed by a carbamate ion intermediate, and that involving direct ionization of an amide hydrogen fo